Barium Nitrate & Sodium Sulphate

By Vincent Summers
fireworks display image by BHughes Photography from

Barium nitrate and sodium sulphate react together to form one soluble salt, sodium nitrate, and an insoluble salt, barium sulphate. Barium sulphate is one of the most insoluble compounds known. Although many reactions are reversible given the proper conditions, since one of the products of this reaction is insoluble in water, the reaction's reversibility is lost.

The Reaction

The chemical reaction may be written Ba(NO3)2 + Na2SO4 ---> 2 NaNO3 + BaSO4

This says that one molecule of barium nitrate reacts with one molecule of sodium sulfate to produce two molecules of sodium nitrate plus one molecule of barium sulfate. The products of the reaction are both of use to the commercial world. The uses for the resultant sodium nitrate and barium sulfate are considerably different from each other.

Uses of Sodium Nitrate

Nitrates are strong oxidizers, and sodium nitrate is used in pyrotechnics and in rocket propellants. In addition, it is an excellent source of nitrogen in fertilizers and is important in various glass and ceramic formulations. Sodium nitrate is also used as an anti-microbial preservative in food products.

Medical Use of Barium Sulphate

Although most sources of barium are of severe toxicity to humans, the sulphate--if pure--is not. This is because of its high degree of insolubility. Barium sulphate is useful as a contrasting agent in X-ray medical technology. It is consumed in the form of a meal or "milkshake."

Other Uses of Barium Sulphate

There are a host of minor uses, most of which employ the compound because of the physical properties of its particles. For example, it may be used to coat molds so metal cast in them will not adhere. Although barium nitrate, one of the starting materials, is often used in pyrotechnics, barium sulphate is also used in certain specialty fireworks.


Use protective equipment. Material safety data sheets should be carefully reviewed before the unfamiliar individual begins to use any of these substances, as barium compounds are highly poisonous, and nitrates are strong oxidizers.

About the Author

Vincent Summers received his Bachelor of Science degree in chemistry from Drexel University in 1973. He furthered his education through the University of Virginia's Citizen Scholar Program program, taking many courses in organic and quantum chemistry. He has written technical articles since 2010.