Difference Between Linear & Branched Polymers

By Kevin Carr
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A polymer is a general term for any molecule that is a long string of smaller repeating parts. In manufacturing, polymers are often thought of as plastics because many artificial substances like plastic are polymers derived from petroleum. However, there are many different polymers (both naturally occurring and artificial) that are made of different parts. Often, the type of polymer chain that forms determines the polymer's properties.

General Polymer Structure

Polymers are made from long, repeating chains of monomers, which are the smallest unique part of the chain. Many common polymers are made from petroleum and other hydrocarbons but others occur naturally. For example, artificial polyethylene is formed from a chain of ethylene molecules, while naturally occurring starch is made from long chains of glucose molecules. Some polymer chains are only a few hundred units long, while others have the potential of being infinitely long. For example, the molecules in natural rubber are so entwined that a whole rubber band can be considered one large polymer molecule.

Linear Polymers

The simplest polymer is a linear polymer. A linear polymer is simply a chain in which all of the monomers exist in a single line. An example of a linear polymer is Teflon, which is made from tetrafluoroethylene. It is a single strand of units made from two carbon atoms and four fluorine atoms. When formed, these linear polymers can create strands of fibers or form a mesh that can be very strong and hard to break through.

Branched Polymers

Branched polymers occur when groups of units branch off from the long polymer chain. These branches are known as side chains and can also be very long groups of repeating structures. Branching polymers can be further categorized by how they branch off from the main chain. Polymers with many branches are known as dendrimers, and these molecules can form a webbing when cooled. This can make the polymer strong in the ideal temperature range. However, when heated, both linear and branched polymers soften as the temperature vibration overcomes the attractive forces between the molecules.

Cross-Linked Polymers

An additional type of polymer is known as the cross-linked polymer. This polymer forms long chains, either branched or linear, that can form covalent bonds between the polymer molecules. Because cross-linked polymers form covalent bonds that are much stronger than the intermolecular forces that attract other polymer chains, the result is a stronger and more stable material. An example of this is when natural rubber is vulcanized, which means it is heated so the sulfur molecules in the rubber polymer chains form covalent bonds with each other. This difference in strength is noticeable when you compare the stiffness, rigidity and durability of a car tire with that of a rubber band.

About the Author

Kevin Carr has been writing for a variety of outlets and companies since 1991. He has contributed to McGraw-Hill textbooks for middle school and high school, written for the Newspaper Network of Central Ohio and has been a featured film critic for online publications including 7M Pictures and Film School Rejects. Carr holds a Bachelor of Science in education.